Description: The catalogue includes 216 topocentric positions of Thebe, Amalthea, Adrastea and Metis derived from the observations made with the 2-m Zeiss RCC telescope of Terskol Observatory in 1999-2000 (longitude=42.50083 degree, latitude=43.27472 degree height=3100m). The Two-Channel Focal Reducer of the Max-Planck Institute for Aeronomy (MPAe,Germany) was used for acquisition of the images. The optical arrangement of this device and the main parameters of the optical system are published in [1]. We provide delta(alpha) and delta(delta) of Thebe and Amalthea with respect to the Galilean satellites, while the positions of Metis and Adrastea are referred to either the Galilean moons or to Thebe or to Amalthea. Since our frames cover the field of the Galilean moons, they were used as the reference points forming the reference direction on the frames. The array scale was corrected by the differential refraction and differential aberration to first order. All observed positions are calculated in the J2000/ICRF reference system and compared with theoretical ones. The precise ephemeris positions of the Galilean satellites, Thebe, Amalthea,Adrastea and Metis were got from HORIZONS Ephemeris System, provided by JPL. Residual statistics show the inner accuracy of our observations in the range from about 0.1 to 0.2 arcsec for Thebe and Amalthea and 0.2-0.9 arcsec for Metis and Adrastea. A dependence of the differences of the observed and calculated positions on the distances from Jupiter has been found for our observations of Metis and Adrastea. [1] Jockers K., Credner T., Bonev T., et al., Kinematika i fizika nebesnyh tel , 2001, in press.